TY - JOUR
T1 - Vibrational coherences and relaxation in the high-spin state of aqueous [FeIIbpy3]2
AU - Consani, C.
AU - Prémont-Schwarz, M.
AU - Elnahhas, A.
AU - Bressler, C.
AU - Van Mourik, F.
AU - Cannizzo, A.
AU - Chergui, M.
PY - 2009
Y1 - 2009
N2 - Femtosecond excitation of the singlet states of aqueous [FeII(bpy)3]2+ (bpy=2,2′-bipyridine) leads to the formation of a vibrationally hot quintet state that exhibits wave-packet dynamics arising from a chelate-ring and bending mode. The vibrational relaxation involves at least two modes: the FeN stretching mode (see picture) and the coherently excited chelate-ring and bending mode, which relax on different time scales.
AB - Femtosecond excitation of the singlet states of aqueous [FeII(bpy)3]2+ (bpy=2,2′-bipyridine) leads to the formation of a vibrationally hot quintet state that exhibits wave-packet dynamics arising from a chelate-ring and bending mode. The vibrational relaxation involves at least two modes: the FeN stretching mode (see picture) and the coherently excited chelate-ring and bending mode, which relax on different time scales.
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-70349917569&partnerID=MN8TOARS
U2 - 10.1002/anie.200902728
DO - 10.1002/anie.200902728
M3 - Article
VL - 48
SP - 7184
EP - 7187
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 39
ER -